Applied Physics I: Chapter 7: Quantum Mechanics

Physical significance of a wave function

Wave function: It is the variable quantity that is associated with a moving particle at any position (x, y, z) and at any time 't' and it relates the probability of finding the particle at that point and at that time.

PHYSICAL SIGNIFICANCE OF A WAVE FUNCTION [ᴪ]

 

Wave function: It is the variable quantity that is associated with a moving particle at any position (x, y, z) and at any time 't' and it relates the probability of finding the particle at that point and at that time.

• It relates the particle and the wave statistically

 (i.e.,) ᴪ(x, y, z, t) = A e-iω( t - x/v )

 (or) ᴪ = ᴪ e‒iωt

• Wave function gives the information about the particle behaviour.

• ᴪ is a complex quantity and individually it does not have any meaning.

• |ᴪ|2= ᴪ*ᴪ is real and positive, it has physical meaning. This concept is similar to light. In light, amplitude may be positive (or) negative but the Intensity, which is the square of amplitude is real and is measurable.

• |ᴪ|2 represents the probability density (or) probability of finding the particle per unit volume.

• For a given volume dτ, the probability of finding the particle is given by Probability (P) = ∫∫∫ |ᴪ|2

where dτ = dx.dy.dz

• The probability will have any value between zero to one. (i.e.,)

(i) If P=0 then there is no chance for finding the particle (i.e.,) there is no particle, within the given limits.

(ii) If P=1 then there is 100% chance for finding the particle (i.e.,) the particle is definitely present, within the given limits.

(iii) If P=0.7, then there is 70% chance for finding the particle and 30% there is no chance for finding the particle, within the given limits.


Example: If a particle is definitely present within a one dimensional box (x‒direction) of length ‘l’, then the probability of finding the particle can be written as

P=01 |ᴪ|2 dx = 1

 

Applied Physics I: Chapter 7: Quantum Mechanics : Tag: Applied Physics : - Physical significance of a wave function


Applied Physics I: Chapter 7: Quantum Mechanics



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